Q.1
14 MarksGlobal warming is the slow rise in the average temperature of the Earth. It is caused mainly by greenhouse gases, such as carbon dioxide (CO) and methane, which are released by the burning of coal, petrol and diesel. These gases trap the heat of the Sun. The effects are melting of ice, a rising sea level and climate change.
Solar energy is the energy of the Sun's rays. It is clean and renewable. It can be changed into electricity by solar cells (photovoltaic) or used for heating water by solar collectors. When solar energy replaces fossil fuels, less CO is released, so it helps to reduce global warming.
The First Law of Thermodynamics says that energy can neither be created nor destroyed. It can only change from one form to another. For a closed system going through a process, its mathematical form is
or, for a very small change, .
Meaning of the terms:
- : the heat supplied to the system. It is positive when heat is added to the system and negative when heat is rejected.
- : the change in the internal energy of the system, . For a perfect gas, .
- : the work done by the system on the surroundings. It is positive when the system does work, and negative when work is done on the system.
All terms are in the same unit, kJ (or J). For a complete cycle, , so . The net heat supplied is equal to the net work done.
Characteristic gas equation: , where is the absolute pressure, is the volume, is the mass, is the absolute temperature and is the characteristic gas constant. It is obtained by combining two laws.
Boyle's law
At a constant temperature, the volume of a given mass of a gas is inversely proportional to its pressure.
Charles's law
At a constant pressure, the volume of a given mass of a gas is directly proportional to its absolute temperature.
Derivation
Let a gas change from the state 1 (, , ) to the state 2 (, , ). We take the gas through two steps, by way of an intermediate state (, , ).
(Boyle's law). The pressure changes from to :
(Charles's law). The temperature changes from to :
Equating the two values of :
For a gas of mass , this constant is . So
For 1 kg of the gas, , where is the specific volume. The value of is different for each gas. For example, kJ/kg K for air. , where kJ/kmol K is the universal gas constant and is the molecular mass.
Example: for 1 kg of air at 300 K and 100 kPa, the specific volume is m/kg.
A perfect gas is an imaginary gas that follows this equation at all pressures and temperatures. Real gases follow it closely at low pressure and high temperature.
Boyle's law and Charles's law together give , which is written as for a perfect gas.