Q.1
14 Marks- Energy: the capacity to do work. It exists in many forms: mechanical (kinetic and potential), heat, electrical and chemical. Its SI unit is the joule (J). Energy can change from one form to another, but cannot be created or destroyed.
- Work: done when a force moves its point of application in the direction of the force. , in joules (1 J = 1 N·m). In thermodynamics, work is energy crossing the boundary of a system, other than heat.
- Power: the rate of doing work, . Its unit is the watt (W), 1 W = 1 J/s. A 1 kW motor does 1000 J of work every second.
First law of thermodynamics: energy can neither be created nor destroyed; it can only change from one form to another. This is the law of conservation of energy applied to heat and work.
For a closed system undergoing a cycle, the net heat supplied equals the net work done:
For a closed system undergoing a process (change of state), the heat supplied is used partly to raise the internal energy and partly to do work:
Here is the heat supplied to the system, is the change in internal energy, and is the work done by the system.
Explanation:
- If heat is supplied and no work is done, the internal energy rises (heating gas in a closed rigid tank).
- If the system is insulated (), work done by it comes from its internal energy, so .
- A machine that produces work continuously without any energy input (PMM1) is impossible.
Example: 100 kJ of heat is given to a gas, and it does 40 kJ of work. Then kJ.
Global warming
Global warming is the long-term rise in the average temperature of the Earth's surface and atmosphere.
Cause: the greenhouse effect. Sunlight passes through the atmosphere and warms the Earth. The warm Earth gives out infrared (heat) radiation. Greenhouse gases absorb this radiation and send part of it back, which keeps the Earth warm. Human activity has greatly increased these gases, so more heat is trapped.
Main greenhouse gases and sources:
| Gas | Main sources |
|---|---|
| Carbon dioxide (CO2) | Burning coal, oil and gas; deforestation |
| Methane (CH4) | Paddy fields, cattle, landfills, gas leaks |
| Nitrous oxide (N2O) | Fertilisers, burning of fuels |
| CFCs and HFCs | Refrigerators, air conditioners, aerosols |
Effects:
- Melting of glaciers and polar ice, and rise in sea level.
- More extreme weather: heat waves, floods, droughts and cyclones.
- Changes in rainfall, which affect agriculture and water supply.
- Loss of species and damage to coral reefs.
- Spread of diseases and health problems.
Remedies: use renewable energy (solar, wind, hydro), improve energy efficiency, plant trees, use public transport and electric vehicles, and replace high global warming refrigerants. International agreements such as the Kyoto Protocol and the Paris Agreement set targets to cut emissions.
Ozone depletion
The ozone layer is a layer of ozone (O3) in the stratosphere, about 15 to 35 km above the Earth. It absorbs harmful ultraviolet (UV-B) radiation from the Sun.
Cause: CFCs (chlorofluorocarbons, used as refrigerants such as R-11 and R-12, and in aerosols and foams), halons (fire extinguishers) and some other chemicals rise to the stratosphere. UV light breaks them and frees chlorine atoms, which destroy ozone in a chain reaction:
One chlorine atom can destroy thousands of ozone molecules. An ozone hole forms over Antarctica every spring.
Effects:
- More UV radiation reaches the Earth, causing skin cancer, cataracts and weaker immunity.
- Damage to crops, plants and marine life (plankton).
Remedies: the Montreal Protocol (1987) phased out CFCs and halons. Refrigeration now uses ozone-friendly refrigerants such as R-134a, R-410A, R-290 (propane) and ammonia. The ozone layer is slowly recovering.
Global warming is the rise in Earth's temperature caused by greenhouse gases such as CO2 and methane trapping heat, while ozone depletion is the thinning of the stratospheric ozone layer by chlorine from CFCs; renewable energy, efficiency and the Paris and Montreal agreements address them.